226890
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226890
Aldrich
2-(Trimethylsilyl)ethanol
99%
| Synonym: | (2-Hydroxyethyl)trimethylsilane |
| CAS Number: | 2916-68-9 |
| Linear Formula: | (CH3)3SiCH2CH2OH |
| Molecular Weight: | 118.25 |
| Beilstein Registry Number: | 1732034 |
| EC Number: | 220-844-5 |
| MDL number: | MFCD00002825 |
| PubChem Substance ID: | 24853596 |
Description
| Application | Used to synthesize Teoc-protected amines via alcoholysis of the corresponding isocyanates.5,6 |
| Protecting reagent for carboxyl1 and phosphate2,3,4 groups. | |
| Packaging | 1, 10, 50 g in glass btl |
Properties
| assay | 99% |
| refractive index | n |
| bp | 71-73 °C/35 mmHg(lit.) |
| density | 0.825 g/mL at 25 °C(lit.) |
Safety
References
| Cited Reference | 1. J. Chem. Soc. Perkin Trans. I, 2639, (1993) |
| 2. J. Org. Chem. 59, 6687, (1994) | |
| 3. Tetrahedron Lett. 35, 757, (1994) | |
| 4. Tetrahedron Lett. 33, 7685, (1992) | |
| 5. Synlett, 2670, (2006) | |
| 6. Org. Lett. 8, 3995, (2006) Abstract | |
| Beilstein | Beil. 4,IV,3951 |
| Fieser | Fieser 8,510 |
| reference | Aldrich MSDS 1, 1798:B / Corp MSDS 1 (2), 3497:B / FT-IR 1 (2), 1108:D / FT-IR 2 (3), 4365:A / FT-NMR 1 (3), 654:A / RegBook 1 (2), 2965:H / Sigma FT-IR 1 (2), 984:A / Structure Index 1, 469:D:4 / Vapor Phase 3, 1638:B |
